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American Chemical Society, Journal of Organic Chemistry, 1(77), p. 772-774, 2011

DOI: 10.1021/jo2021407

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Enantioselective Total Synthesis of (+)-Scuteflorin A Using Organocatalytic Asymmetric Epoxidation

Journal article published in 2011 by Christopher J. Bartlett, David P. Day, Yohan Chan, Steven M. Allin, Michael J. McKenzie, Alexandra M. Z. Slawin ORCID, Philip C. Bulman Page
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This paper is available in a repository.

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Abstract

We report the first enantioselective total synthesis of (+)-scuteflorin A in 14% overall yield, employing a chiral iminium salt to effect an organocatalytic asymmetric epoxidation of xanthyletin in >99% ee as the key step.