The Use of a Bis(phenylpyrazolyl)pyridyl Ligand to Prepare [Mn4] and [Mn10] Cage Complexes
Journal article published in 2011 by
José Sánchez Costa,
Gavin A. Craig 
,
Leoní A. Barrios,
Olivier Roubeau,
Eliseo Ruiz ,
Silvia Gómez-Coca,
Simon J. Teat,
Guillem Aromí
,
Leoní A. Barrios,
Olivier Roubeau,
Eliseo Ruiz ,
Silvia Gómez-Coca,
Simon J. Teat,
Guillem Aromí
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Abstract
Rational design versus serendipity: The first two high-nuclearity Mn II/III clusters with a novel extended bis(phenylpyrazolyl) pyridyl ligand (see graphic) are described in a promising route for the preparation of new magnetic coordination aggregates, differing from conventional methods involving small bridging ligands.