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Institute of Organic Chemistry & Biochemistry, Collection of Czechoslovak Chemical Communications, 8(72), p. 1005-1013

DOI: 10.1135/cccc20071005

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Exploring the Substrate Scope of the Ru(II)-Catalyzed Kharasch Reaction

Journal article published in 2007 by Eskender Mume, Ian J. Munslow, Klas Källström, Pher G. Andersson ORCID
This paper was not found in any repository; the policy of its publisher is unknown or unclear.
This paper was not found in any repository; the policy of its publisher is unknown or unclear.

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Abstract

The Kharasch reaction, or atom-transfer addition of polyhalogenated alkanes to alkenes is known to be catalyzed by a number of Ru(II) complexes. The easily prepared [RuCl2(PPh3)3] was used to investigate the reaction scope. A number of halogenated alkanes were added to a range of alkenes with good to excellent regioselectivities.