A study of D2H+ ions in their lowest rotational states is presented. The ions are generated in pulsed discharge in liquid N2 cooled He/Ar/H2/D2 gas mixture. Near infrared (NIR) second overtone transitions in the 6534–6536cm−1 (1.529–1.530μm) region are used to identify the ions and determine their degree of rotational excitation. The data were obtained using NIR cavity ringdown absorption spectroscopy (NIR-CRDS). The sensitivity obtained was typically 5×10−9cm−1. The measured second overtone transition frequencies are in very good agreement (better than 0.02cm−1) with ab initio predictions. From the Doppler broadening the kinetic temperature of ions is estimated to be (220±50) K. The absolute number density of D2H+ as a function of H2/D2 mixing ratio and time is measured.