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American Chemical Society, Journal of Organic Chemistry, 22(78), p. 11508-11512, 2013

DOI: 10.1021/jo4020744

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Substituent Effects on the Catalytic Activity of Bipyrrolidine-Based Iron Complexes

Journal article published in 2013 by Giorgio Olivo ORCID, Osvaldo Lanzalunga, Luigi Mandolini, Stefano Di Stefano
This paper is available in a repository.
This paper is available in a repository.

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Abstract

The catalytic activity and the selectivity of new bipyrrolidine based Fe(II) complexes 2.Fe(OTf)2 and 3.Fe(OTf)2 in the oxidation of a series of alkyl and alkenyl hydrocarbons as well as of an aromatic sulfide with H2O2 were tested and compared with the catalytic efficiency of White's parent complex 1.Fe(OTf)2 in order to evaluate the sensitivity of the reaction to electronic effects.