Elsevier, Applied Surface Science, (380), p. 210-217, 2016
DOI: 10.1016/j.apsusc.2016.01.156
Full text: Download
Three-dimensional titania network was in-situ constructed on Ti foil via sequential acid and hydrogen peroxide treatments. The titania network was pure anatase phase and homogeneously covered on the titanium grain surface, which largely enhanced the roughness of the Ti foil. The as-received Ti foil and the treated one were used as the flexible substrates of DSSCs, and energy conversion efficiencies of 3.74% and 4.98% were obtained, respectively. Such remarkable increment can be ascribed to the good electrical contact between the nanocrystalline TiO2 and the Ti foil, the improved electron percolation pathways and recombination inhibition of electrons in Ti substrate with triiodide ions in electrolyte. Flexible DSSCs based on the treated Ti foil showed relatively good mechanical stability, which exhibited 97.3% retention of the initial efficieny after twenty consecutive bending.