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Wiley, Angewandte Chemie, 14(123), p. 3236-3239, 2011

DOI: 10.1002/ange.201007583

Wiley, Angewandte Chemie International Edition, 14(50), p. 3178-3181

DOI: 10.1002/anie.201007583

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A Metal-Organic Framework with Optimized Open Metal Sites and Pore Spaces for High Methane Storage at Room Temperature

This paper is available in a repository.
This paper is available in a repository.

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Data provided by SHERPA/RoMEO

Abstract

Holey MOF! Open copper sites and optimal pore spaces in UTSA-20 (see picture), a MOF based on the novel trinodal (3,3,4) net, has made UTSA-20 into the material with the highest methane storage density (0.22-gcm-3) in micropores, and one of the few porous MOFs with storage volume capacity (195-cm3cm-3) surpassing the DOE methane target of 180-cm3cm-3 at room temperature and 35-bar.