Wiley, Angewandte Chemie, 14(123), p. 3236-3239, 2011
Wiley, Angewandte Chemie International Edition, 14(50), p. 3178-3181
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Holey MOF! Open copper sites and optimal pore spaces in UTSA-20 (see picture), a MOF based on the novel trinodal (3,3,4) net, has made UTSA-20 into the material with the highest methane storage density (0.22-gcm-3) in micropores, and one of the few porous MOFs with storage volume capacity (195-cm3cm-3) surpassing the DOE methane target of 180-cm3cm-3 at room temperature and 35-bar.