Published in
Elsevier, Tetrahedron Letters, 48(48), p. 8430-8433
DOI: 10.1016/j.tetlet.2007.09.167
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An investigation of the complexation of a TTF derivative with α-, β- and γ-cyclodextrins in aqueous media
Journal article published in 2007 by
Marc Bria,
Graeme Cooke 
,
Alan Cooper,
François Delattre,
Shanika Gunatilaka Hewage,
Gouher Rabani,
Margaret Nutley,
Patrice Woisel
,
Alan Cooper,
François Delattre,
Shanika Gunatilaka Hewage,
Gouher Rabani,
Margaret Nutley,
Patrice Woisel
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Abstract
This Letter, describes the complexation of α-, β- and γ-cyclodextrins (1–3) with TTF derivative 4 in water. In particular, we show using 1H, 13C NMR, UV–vis spectroscopy and isothermal titration calorimetry that β-cyclodextrin 2 forms an effective complex with 4. Complex 2·4 can be conveniently disassembled upon the addition of 1-adamantanol.