Published in

Wiley, Angewandte Chemie International Edition, 14(50), p. 3313-3317, 2011

DOI: 10.1002/anie.201006639

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Dissolved Carbon Controls the Initial Stages of Nanocarbon Growth

This paper is available in a repository.
This paper is available in a repository.

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Abstract

Sneaked in: Carbon atoms from defective supports are incorporated in nickel nanoparticles at relatively low temperatures (for example in a Ni(100) surface; Ni brown, C black) The dissolved carbon not only modifies the electronic properties of the metal but it also leads to a reconstruction of the nanoparticles. These findings may explain many of the differences in catalytic activity observed when supporting metals on carbon.