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International Union of Crystallography, Acta Crystallographica Section E: Structure Reports Online, 2(63), p. m372-m375, 2007

DOI: 10.1107/s1600536806054675

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Decaaquadioxobis[μ3-N-(phosphonomethyl)iminodiacetato]dimanganesedivanadium dihydrate

Journal article published in 2007 by Luís Cunha-Silva ORCID, Fa-Nian Shi ORCID, Jacek Klinowski, Tito Trindade, João Rocha ORCID, Filipe A. Almeida Paz
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

The crystal structure of the title compound, [Mn2V2(C5H6NO7P)2O2(H2O)10]·2H2O, contains a centrosymmetric dimeric [V2O2(pmida)2]4− unit [where H4pmida is N-(phosphono­meth­yl)imino­diacetic acid] connecting two neighbouring Mn2+ cations through the phospho­nate groups. The crystal structure is characterized by the presence of an extensive network of strong and highly directional O—H⋯O hydrogen bonds, involving the water mol­ecules (coordinated and uncoordinated) and the functional groups of pmida4−.