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Beilstein-Institut, Beilstein Journal of Organic Chemistry, (10), p. 2704-2714, 2014

DOI: 10.3762/bjoc.10.285

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Synthesis and properties of novel star-shaped oligofluorene conjugated systems with BODIPY cores

Journal article published in 2014 by Clara Orofino-Pena, Diego Cortizo-Lacalle, Joseph Cameron, Muhammad T. Sajjad, Pavlos P. Manousiadis, Neil J. Findlay ORCID, Alexander L. Kanibolotsky, Dimali Amarasinghe, Peter J. Skabara, Tell Tuttle, Graham A. Turnbull ORCID, Ifor D. W. Samuel
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

Star-shaped conjugated systems with varying oligofluorene arm length and substitution patterns of the central BODIPY core have been synthesised, leading to two families of compounds, T-B1–T-B4 and Y-B1–Y-B4, with T- and Y-shaped motifs, respectively. Thermal stability, cyclic voltammetry, absorption and photoluminescence spectroscopy of each member of these two families were studied in order to determine their suitability as emissive materials in photonic applications.