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Elsevier, Tetrahedron, 46(67), p. 8902-8909, 2011

DOI: 10.1016/j.tet.2011.09.051

Wiley-VCH Verlag, ChemInform, 12(43), p. no-no, 2012

DOI: 10.1002/chin.201212124

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Diels–Alder reactions of 3-(1H-tetrazol-5-yl)-nitrosoalkenes: synthesis of functionalized 5-(substituted)-1H-tetrazoles

Journal article published in 2011 by Susana M. M. Lopes ORCID, Francisco Palacios, Américo Lemos, Teresa M. V. D. Pinho e. Melo ORCID
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This paper is available in a repository.

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Abstract

a b s t r a c t A general route to 1,2-oxazines and open chain oximes bearing a 1H-tetrazolyl substituent via DielseAlder reaction of 3-(tetrazol-5-yl)-nitrosoalkenes is reported. It was also demonstrated that reduction of these adducts followed by deprotection of the tetrazolyl group give 5-(1-aminoalkyl)-1H-tetrazoles, a-amino acid analogues.