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American Physical Society, Physical Review Letters, 4(103), 2009

DOI: 10.1103/physrevlett.103.047601

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Coexistence of Weak Ferromagnetism and Ferroelectricity in the High PressureLiNbO3-Type Phase ofFeTiO3

This paper is available in a repository.
This paper is available in a repository.

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Abstract

We report the magnetic and electrical characteristics of polycrystalline FeTiO_{3} synthesized at high pressure that is isostructural with acentric LiNbO_{3} (LBO). Piezoresponse force microscopy, optical second harmonic generation, and magnetometry demonstrate ferroelectricity at and below room temperature and weak ferromagnetism below approximately 120 K. These results validate symmetry-based criteria and first-principles calculations of the coexistence of ferroelectricity and weak ferromagnetism in a series of transition metal titanates crystallizing in the LBO structure.