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Elsevier, Applied Surface Science, (175-176), p. 62-68

DOI: 10.1016/s0169-4332(01)00159-3

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Terrace-width distributions on vicinal surfaces: Generalized Wigner surmise and extraction of step-step repulsions

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This paper is available in a repository.

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Abstract

From quantitative measurement of the equilibrium terrace-width (l) distribution (TWD) of vicinal surfaces, one can assess the strength A of elastic step-step repulsions A/l(2). Generally the TWD depends only on (A) over bar = A x (step stiffness)/(k(B)T)(2) From ideas of fluctuation phenomena, TWDs should be describable by the "generalized Wigner distribution" (GWD), essentially a power-law in l/ times a "Gaussian decay" in l/ . The power-law exponent is related simply to A. Alternatively, the GWD gives the exact solution for a mean-field approximation. The GWD provides at least as good a description of TWDs as the standard fit to a Gaussian (centered at ). It works well for weak elastic repulsion strengths A (where Gaussians fail), as illustrated explicitly for vicinal Pt(l 1 0). Application to vicinal copper surfaces confirms the viability of the GWD analysis. The GWD can be treated as a two-parameter fit by scaling e using an adjustable characteristic width. With Monte Carlo and transfer-matrix calculations, we show that for physical values of (A) over bar the GWD provides a better overall estimate than the Gaussian models. We quantify how a GWD approaches a Gaussian for large (A) over bar and present a convenient, accurate expression relating the variance of the TWD to A. We describe how discreteness of terrace widths impacts the standard continuum analysis. (C) 2001 Elsevier Science B.V. All rights reserved.