Published in

Wiley, Angewandte Chemie International Edition, 27(48), p. 4982-4985, 2009

DOI: 10.1002/anie.200900426

Wiley, Angewandte Chemie, 27(121), p. 5082-5085, 2009

DOI: 10.1002/ange.200900426

Links

Tools

Export citation

Search in Google Scholar

Chemical Infiltration during Atomic Layer Deposition: Metalation of Porphyrins as Model Substrates

This paper is available in a repository.
This paper is available in a repository.

Full text: Download

Green circle
Preprint: archiving allowed
Orange circle
Postprint: archiving restricted
Red circle
Published version: archiving forbidden
Data provided by SHERPA/RoMEO

Abstract

New uses for ALD: By applying standard metal oxide atomic layer deposition (ALD) to two types of porphyrins, site-specific chemical infiltration of substrate molecules is achieved: Diethylzinc can diffuse into the interior of porphyrin supramolecular structures and induce metalation of the porphyrin molecules from the vapor phase. A = Ph, p-HO(3)SC(6)H(4).