Wiley, Angewandte Chemie International Edition, 27(48), p. 4982-4985, 2009
Wiley, Angewandte Chemie, 27(121), p. 5082-5085, 2009
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New uses for ALD: By applying standard metal oxide atomic layer deposition (ALD) to two types of porphyrins, site-specific chemical infiltration of substrate molecules is achieved: Diethylzinc can diffuse into the interior of porphyrin supramolecular structures and induce metalation of the porphyrin molecules from the vapor phase. A = Ph, p-HO(3)SC(6)H(4).