Published in

SAGE Publications, Journal of Chemical Research, 2(2003), p. 54-55, 2003

DOI: 10.3184/030823403103173101

Wiley-VCH Verlag, ChemInform, 33(34), 2003

DOI: 10.1002/chin.200333182

Journal of Chemical Research (Miniprint), 2(2003), p. 54-55

DOI: 10.3184/030823503103174938

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An efficient synthetic approach to the aromatic sesquiterpenoids via a SmI2-promoted construction of quaternary centre

Journal article published in 2003 by Xue Zhi Zhao ORCID, Yan Xing Jia, Yong Qiang Tu
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

The total synthesis of the natural (±)-cuparene (1) and (±)-herbertene (2) has been carried out in eight steps from 2-cyclohexen-1-one (3) via a key quaternary carbon centre construction using a SmI2-promoted rearrangement of 2,3-epoxy alcohol.