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Elsevier, Tetrahedron, 8(53), p. 2899-2906

DOI: 10.1016/s0040-4020(97)00023-9

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Addition of Reformatsky reagents to 1,1-dicyanoalkenes

Journal article published in 1997 by Yu Ding, Zongbao Zhao ORCID, Chengming Zhou
This paper is available in a repository.
This paper is available in a repository.

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Abstract

Reformatsky reagents are found to react with different 1,1-dicyanoalkenes to afford addition products, and the reaction can be conducted more efficiently in the presence of a catalytic amount of Cp2TiCl2. There is strong evidence to support a SET process in the course of Reformatsky reagent formation.