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Elsevier, Marine and Petroleum Geology, (68), p. 269-290

DOI: 10.1016/j.marpetgeo.2015.08.034

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Hydrocarbon potential and depositional environments of Oligo-Miocene rocks in the Eastern Carpathians (Vrancea Nappe, Romania)

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This paper is available in a repository.

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Abstract

The Eggerding Formation, typically about 45 m thick, forms part of the deep marine Oligocene succession in the Molasse Basin, which comprises from bottom to top the Schöneck (formerly "Fish Shale"), Dynow ("Bright Marlstone"), Eggerding ("Banded Marl") and Zupfing formations ("Rupelian Marl"). The Eggerding Formation and the lower part of the Zupfing Formation have been studied using core and cuttings samples and a multidisciplinary approach involving core description, geochemistry, palynology and nanno-paleontology. The Dynow Formation and the lower part of the Eggerding Formation were deposited during nannoplankton zone NP23 (Martini, 1971). The transition between the Dynow and Eggerding formations is characterized by a gradual decrease in carbonate contents. The Eggerding Formation deposited in near-shore environments contains several sand layers. In contrast, the Eggerding Formation deposited along the northern slope is generally poor in sand. Its lower part consists of dark grey laminated shaly marlstone with white bands rich in coccolithophorides. TOC contents are about 5 %. The upper part of the Eggerding Formation consists of a homogenous sequence of marly shale and includes in average 1.6 % TOC. Oxygen deficient conditions prevailed during deposition of the Eggerding Formation. Marine palynomorphs are present in all samples from the Eggerding Formation, but calcareous nannoplankton is restricted to its lower part. Salinity variations are recorded in rocks of the lower part of the Eggerding Formation. The environment during deposition of its upper part was more stable. Log signatures, which are comparable over tens of kilometres, provide evidence for the lateral continuity of the Eggerding Formation deposited on the upper slope. Slope instabilities are indicated by slumps and extensive submarine slides. Sliding reached a maximum at the transition from the Eggerding to the Zupfing Formation, when locally a succession up to 70 m thick was removed from the northern slope. The slided material was redeposited either on the northern slope or at the base of the slope. The Eggerding Formation is overlain by the Zupfing Formation (NP24), consisting of clay marl up to 450 m thick. Oxygen-depleted conditions continued during deposition of the Zupfing Formation, but only the lowermost few meters of the Zupfing Formation ("Transition Zone") are rich in organic matter (1.5 % TOC). Whereas the lower part of the Eggerding Formation (TOC 1.9-6.0 %; HI up to 600 mg HC/g TOC) holds a very good source potential for oil (and gas), its upper part and the Transition Zone (TOC: ~1.5 %; "true" HI 500-600 mg HC/g TOC) are characterized by a good potential. Biomarker data suggest that the latter contributed significantly to the Molasse oils. In contrast, the contribution of the Dynow Formation and the lower Eggerding Formation was minor.