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American Chemical Society, Inorganic Chemistry, 15(45), p. 5718-5720, 2006

DOI: 10.1021/ic060437t

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Hydrogen Adsorption in an Interpenetrated Dynamic Metal−Organic Framework

Journal article published in 2006 by Banglin Chen, Shengqian Ma ORCID, Shengqian, Fatima Zapata, Emil B. Lobkovsky, Jun Yang
This paper is available in a repository.
This paper is available in a repository.

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Abstract

A metal-organic framework Zn(NDC)(4,4'-Bpe)(0.5).xG [NDC = 2,6-naphthalenedicarboxylate; 4,4'-Bpe = 4,4'-trans-bis(4-pyridyl)ethylene; G = guest molecules] has been synthesized, structurally characterized, and rationalized to be a two-interpenetrated elongated primitive cubic net. Powder X-ray diffraction and adsorption studies reveal the dynamic feature of the framework, which can take up hydrogen of about 2.0 wt % at 77 K and 40 bar and 0.3 wt % at 298 K and 65 bar.