Polypropylene nonwoven materials have foundenormous usefulness in many applications. In this paper, the cyclonic plasma processing at atmospheric pressure was used to determine the surface treatment effect. The change of hydrophilicity was determined by contact angle analysis. The nonwoven polypropylene (NWPP) surface became greatly hydrophilic when exposed to the cyclonic plasma at atmospheric-pressure. A major effect in the surface free energy of material surface due to crosslinking via activated species of inert gases effect was observed. The variations in the chemical structure and surface morphology of the NWPP were confirmed by X-ray photoelectron spectroscopy (XPS) and scanning electron microscope detections. The XPS detection reveals considerably more surface elemental composition of oxygen atoms for cyclonic plasma-modified NWPP.