Published in

American Chemical Society, Journal of Physical Chemistry B (Soft Condensed Matter and Biophysical Chemistry), 25(111), p. 6978-6982, 2007

DOI: 10.1021/jp072540p

Links

Tools

Export citation

Search in Google Scholar

How Solvent Controls Electronic Energy Transfer and Light Harvesting

This paper is available in a repository.
This paper is available in a repository.

Full text: Download

Green circle
Preprint: archiving allowed
  • Must obtain written permission from Editor
  • Must not violate ACS ethical Guidelines
Orange circle
Postprint: archiving restricted
  • Must obtain written permission from Editor
  • Must not violate ACS ethical Guidelines
Red circle
Published version: archiving forbidden
Data provided by SHERPA/RoMEO

Abstract

The way that solvent (or host medium) modifies the rate of electronic energy transfer (EET) has eluded researchers for decades. By applying quantum chemical methods that account for the way solvent (in general any host medium including liquid, solid, or protein, etc.) responds to the interaction between transition densities, we quantify the solvent screening. We find that it attains a striking exponential attenuation at separations less than about 20 angstrom, thus interpolating between the limits of no apparent screening and a significant attenuation of the EET rate. That observation reveals a previously unidentified contribution to the distance dependence of the EET rate.