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American Institute of Physics, Applied Physics Letters, 19(102), p. 192110

DOI: 10.1063/1.4807288

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Chemical identification of luminescence due to Sn and Sb in ZnO

Journal article published in 2013 by Joseph Cullen, Daragh Byrne, K. Johnston ORCID, Enda McGlynn, Martin O. Henry
This paper is available in a repository.
This paper is available in a repository.

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Abstract

We show that the I10 line in ZnO photoluminescence is associated with Sn impurities. The evidence comes from material implanted with radioactive 117Ag, which decays through 117Cd and 117In to stable 117Sn, and 121Ag which decays through the same chain to stable 121Sb. Supporting evidence is provided by ZnO:Sn prepared by the in-diffusion of stable Sn. The I2 and I9 lines are also shown conclusively to be due to In, confirming earlier identifications in the literature. We also observe shallow bound exciton emission at 3.3643(3) eV due to Sb impurities produced at the end of the decay chain of 121Ag.