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American Chemical Society, Journal of Organic Chemistry, 9(76), p. 3588-3593, 2011

DOI: 10.1021/jo200347j

Wiley-VCH Verlag, ChemInform, 31(42), p. no-no, 2011

DOI: 10.1002/chin.201131078

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Nickel-Mediated Decarbonylative Cross-Coupling of Phthalimides with in Situ Generated Diorganozinc Reagents

Journal article published in 2011 by Sarah E. Havlik, Jessica M. Simmons, Valerie J. Winton ORCID, Jeffrey B. Johnson
This paper was not found in any repository; the policy of its publisher is unknown or unclear.
This paper was not found in any repository; the policy of its publisher is unknown or unclear.

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Abstract

The nickel-mediated cross-coupling of phthalimides with diorganozinc reagents proceeds via a decarbonylative process to produce ortho-substituted benzamides in high yields. In addition to tolerating diverse phthalimide functionality, including alkyl, aryl, and heteroatom containing substituents, this methodology proceeds smoothly with diorganozinc reagents prepared from aryl bromides and utilized without purification.