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American Chemical Society, Langmuir, 9(20), p. 3498-3500, 2004

DOI: 10.1021/la049685x

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Direct Evidence for Breakup of Liquid Fibrils via Rayleigh Instabilities in Model Polymer Blends in Step-up Experiments

Journal article published in 2004 by Ellen Van Hemelrijck, Peter Van Puyvelde ORCID, Paula Moldenaers
This paper was not found in any repository; the policy of its publisher is unknown or unclear.
This paper was not found in any repository; the policy of its publisher is unknown or unclear.

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Abstract

Droplet breakup in immiscible polymer blends after a sudden substantial increase in shear rate is studied using small-angle light scattering experiments. During the breakup of the fibrils, secondary streaks are visible in the scattering pattern, which indicate the occurrence of Rayleigh instabilities. A high-resolution camera allows quantitative determination of the evolution of the wavelength of the disturbances during the disintegration process. It is shown that this process is time-controlled rather than strain-controlled as suggested by theory.