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Wiley, Angewandte Chemie International Edition, 37(51), p. 9448-9452, 2012

DOI: 10.1002/anie.201203078

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The Role of Co-Adsorbed CO and OH in the Electrooxidation of Formic Acid on Pt(111)

Journal article published in 2012 by Wang Gao, Jonathan E. Mueller, Qing Jiang ORCID, Timo Jacob
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This paper is available in a repository.

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Abstract

Synergy with potential: Analysis of relevant mechanistic pathways by density functional theory, reveals the synergistic role of co-adsorbed CO and OH in promoting HCOOH electrooxidation on Pt(111). Kinetic models derived from these studies show the atomistic surface phenomena underlying the experimental CV observation in the potential range between 0.0 and 1.2 V.