Published in
Michigan Publishing, Arkivoc, 3(2011), p. 33-41, 2010
DOI: 10.3998/ark.5550190.0012.304
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A synthetic route to pyranoid epoxy-exo-glycals from D-glucose
Journal article published in 2010 by
Ana M. Gómez 
,
Ana Pedregosa,
J. Cristobal López,
Ana Pedregoza,
J. Cristóbal López,
Serafín Valverde
,
Ana Pedregosa,
J. Cristobal López,
Ana Pedregoza,
J. Cristóbal López,
Serafín Valverde
This paper is made freely available by the publisher.
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Abstract
A synthetic route to a pyranose derived epoxy-exo-glycal has been developed from D-glucose. An attempted, one-pot bromination-elimination-oxirane formation, protocol that had worked well on furanoses, resulted only in the generation of 2-bromo-C-1-methyl pyranoid glycals.