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Springer, Transition Metal Chemistry, 3(30), p. 294-298, 2005

DOI: 10.1007/s11243-004-4578-6

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Hydrothermal synthesis and crystal structure of a novel 2-D polymeric manganese (II) complex with mixed ligands

Journal article published in 2005 by You-Wei Yao, Hao-Xiang Lin, Xiao-Dan Sun, Hui-Zhong Kou, Qiang Cai, Heng De Li, Heng-De Li, Ran-Bo Yu ORCID, Dan Wang
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

A novel polymeric complex, [Mn(phen)(pdc)]∞ (phen=1,10-phenanthroline, H2pdc=2,5-pyridinedicarboxylic acid) has been synthesized from the hydrothermal reaction system of H2pdc, phen, MnO2, and H2O. [Mn(phen)(pdc)]∞ is characteristic of an edge-sharing dinuclear MnII structure unit bridged by pdc, leading to a 2-D framework whose stacking is based on weak H-bond interaction. The temperature dependence of the magnetic susceptibility for [Mn(phen)(pdc)]∞ indicates antiferromagnetic coupling [J = −2.76(4)cm−1] between the adjacent paramagnetic MnII ions.