Published in
Royal Society of Chemistry, RSC Advances, 79(5), p. 64503-64513, 2015
DOI: 10.1039/c5ra11402k
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Synthesis of half-titanocenes containing 1,3-imidazolidin-2-iminato ligands of type, Cp*TiCl2[1,3-R2(CH2N)2CN]: highly active catalyst precursors in ethylene (co)polymerisation
Journal article published in 2015 by
Kotohiro Nomura 
,
Srisuda Patamma,
Hideshi Matsuda,
Shohei Katao,
Ken Tsutsumi,
Hiroya Fukuda
,
Srisuda Patamma,
Hideshi Matsuda,
Shohei Katao,
Ken Tsutsumi,
Hiroya Fukuda
This paper is made freely available by the publisher.
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Abstract
Cp*TiCl2[1,3-(2,6-Me2C6H3)2(CH2N)2CN] showed remarkable catalytic activities for ethylene/1-hexene copolymerisation with efficient comonomer incorporation (ex. activity 1 750 000 kg-polymer per mol-Ti per h).