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Royal Society of Chemistry, RSC Advances, 62(5), p. 50113-50117, 2015

DOI: 10.1039/c5ra06773a

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Unexpected CN bond formation via NaI-catalyzed oxidative de-tetra-hydrogenative cross-couplings between N,N-dimethyl aniline and sulfamides

This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

A direct de-tetra-hydrogenative cross-coupling reaction between Csp3–H bonds and sulfamide under transition-metal-free conditions is reported to give the corresponding amidines.