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Royal Society of Chemistry, RSC Advances, 75(5), p. 60898-60907, 2015

DOI: 10.1039/c5ra03947a

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Phosphonium-based tetrakis dibenzoylmethane Eu(iii) and Sm(iii) complexes: synthesis, crystal structure and photoluminescence properties in a weakly coordinating phosphonium ionic liquid

Journal article published in 2015 by C. M. Malba, F. Enrichi, M. Facchin, N. Demitri, J. R. Plaisier, M. M. Natile, M. Selva, P. Riello, A. Perosa ORCID, A. Benedetti
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

Luminescent anionic β-diketonate complexes of formula [P8,8,8,1][Ln(dbm)4], (Ln = Eu3+ and Sm3+, [P8,8,8,1] = trioctylmethylphosphonium and dbm = 1,3-diphenylpropane-1,3-dione) were synthesized, characterized and their photoluminescence properties studied.