Royal Society of Chemistry, RSC Advances, 37(5), p. 29505-29508
DOI: 10.1039/c5ra02756j
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A porous cobalt-based metal–organic framework [CoL2−]n has been designed by self-assembling [Co2(COO)4] paddlewheel SBUs and a novel trigonal hetero–functional ligand. [CoL2−]n exhibits large CO2 uptake and selectivity.