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Wiley, Journal of Applied Polymer Science, 1(115), p. 72-78, 2010

DOI: 10.1002/app.30609

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Synthesis and Characterization of Novel Pour Point Depressants Based on Maleic Anhydride-Alkyl Acrylates Terpolymers

Journal article published in 2010 by Rasha A. El Ghazawy ORCID, Reem K. Farag
This paper is available in a repository.
This paper is available in a repository.

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Abstract

The (Docosanyl acrylate-co-(octadecyl or hexadecyl acrylate)-co-maleic anhydride) terpolymers were prepared using different compositions of the used alkyl acrylates (namely, 90 : 10, 70 : 30, 50 : 50, 30 : 70, and 10 : 90) (DCA-ODA)/(MA) or (DCA-HDA)/(MA). The efficiency of these terpolymers as pour point depressants was discussed. Two western desert waxy crude oils with different wax content were used for evaluation. Correlation between pour point depression efficiency and rheological properties were performed. Rheological parameters were also computed and discussed. It was observed that the synthesized terpolymers showed non-Newtonian pseudoplastic relationships at different concentrations of synthesized terpolymeres with monomer feed ratios of (DCA-ODA (1 : 1))/(MA) or (DCA-HDA (1 : 1))/(MA) = 90/10 mole %. This ratio showed a good ability to disperse wax crystals and improve the flow behaviors of tested two crude oils even at low temperatures below their pour points. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2010