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MDPI, Molecules, 8(20), p. 14522-14532, 2015

DOI: 10.3390/molecules200814522

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Direct Exchange of Oxygen and Selenium Atoms in the 1,2,5-Oxadiazoles and 1,2,5-Selenadiazoles by Action of Sulfur Monochloride

Journal article published in 2015 by Lidia S. Konstantinova, Ekaterina A. Knyazeva, Oleg A. Rakitin ORCID
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

A short synthetic approach to fused 1,2,5-thiadiazoles from the corresponding 1,2,5-oxadiazoles and 1,2,5-selenadiazoles has been developed. Mono- and bis(1,2,5-thiadiazoles) were selectively obtained in high yields. The pathways for these novel reactions were discussed.