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Wiley, Chemistry - A European Journal, 7(17), p. 2138-2145, 2011

DOI: 10.1002/chem.201002069

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Pentanary Cross-Diffusion in Water-in-Oil Microemulsions Loaded with Two Components of the Belousov-Zhabotinsky Reaction

Journal article published in 2011 by Federico Rossi ORCID, Vladimir K. Vanag, Irving R. Epstein
This paper is available in a repository.
This paper is available in a repository.

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Abstract

We measure cross-diffusion coefficients in a five-component system, an aerosol OT (AOT) water-in-oil microemulsion loaded with two constituents of the Belousov-Zhabotinsky (BZ) reaction (H(2) O/AOT/BZ1/BZ2/octane). The species BZ1 is either NaBr, an inhibitor of the BZ reaction, or ferroin, a catalyst for the reaction. As species BZ2, we choose Br(2) , an intermediate in the reaction. The cross-diffusion coefficients between BZ1 and BZ2 are found to be negative, which can be understood in terms of complexation between these species. Using a four-variable model for the BZ reaction, we find that the cross-diffusion coefficients measured here can lead to a noticeable shift in the onset of Turing instability in the BZ-AOT system.