An investigation into the use of zwitterionic ion chromatography for the determination of inorganic anions in water samples was carried out. When using an ODS stationary phase precoated with Zwittergent 3-14 and a pure water mobile phase, the stability of the adsorbed coating was insufficient for quantitative work. Recycling of the water mobile phase was used to stabilise the zwitterionic coating, and resulted in improved retention time precision (15.2% RSD down to 2.4% RSD for nitrate). Post-detection cation- and anion-exchange columns in acid and hydroxide form removed sample ions from the recycling mobile phase, with the desorbed Zwittergent 3-14 passing through unretained and passing back through the pump to the analytical column. A 200-ml volume of mobile phase was recycled over a 3-week period with retention times for sulphate, chloride and nitrate standards injected at the start and end of the period varying less than 2.5%. The same system was then used with a mobile phase containing 2 mM Zwittergent 3-14. This resulted in further improvements in retention time (0.2-0.5% RSD, n = 10) and peak area precision (2.6-6.0% RSD, 1 mM standards) and improved peak efficiencies (2421-4047 N). The developed method was applied to water samples, and results compared to those obtained using anion-exchange chromatography. All sample cations were exchanged to sodium using an off-line cation-exchange procedure prior to injection.