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American Chemical Society, Organometallics, 14(24), p. 3401-3406, 2005

DOI: 10.1021/om050058s

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Reactions of Pd(PPh<sub>3</sub>)<sub>4</sub> with 3‘,5‘-Di-O-acetylthymidine: Oxidative Addition of Pd(PPh<sub>3</sub>)<sub>4</sub> on Thymidine N3 and C4 Atoms

Journal article published in 2005 by Alessandra Romanelli, Rosa Iacovino ORCID, Gennaro Piccialli, Francesco Ruffo, Lorenzo De Napoli, Carlo Pedone, Benedetto Di Blasio, Anna Messere
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Oxidative addition reactions of Pd(PPh3)4 on the pyrimidine nucleosides 3‘,5‘-di-O-acetylthymidine and 3‘,5‘-di-O-acetyl-4-chlorothymidine and on the nucleobase 1-methylthymine have been investigated. N3 and C4 metal coordinated complexes 3 and 7 were isolated and characterized by spectroscopic techniques. Moreover, the crystal structure of the trans-[PdCl(1-methyl thymine)(PPh3)2]·H2O (4) is reported.