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Elsevier, Polyhedron, 7(26), p. 1505-1513

DOI: 10.1016/j.poly.2006.11.025

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Synthesis and characterisation of trisarylphosphine selenides: Further insight into the effect of fluoroalkylation on the electronic properties of trisarylphosphines

Journal article published in 2007 by Dj Adams ORCID, Ja Bennett, Daniel Duncan, Eg Hope, Jonathan Hopewell, Am Stuart, Aj West
This paper is available in a repository.
This paper is available in a repository.

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Abstract

Variations in the magnitude of the 1JSeP coupling constants for a range of phosphorus(V) selenides allow the efficiency of different spacer groups at insulating the phosphorus centre in triarylphosphines from highly electron-withdrawing perfluoroalkyl groups to be established.