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American Chemical Society, Journal of the American Chemical Society, 44(128), p. 14274-14275, 2006

DOI: 10.1021/ja066220f

Wiley-VCH Verlag, ChemInform, 10(38), 2007

DOI: 10.1002/chin.200710085

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A Gold-Catalyzed Unique Cycloisomerization of 1,5-Enynes: Efficient Formation of 1-Carboxycyclohexa-1,4-dienes and Carboxyarenes

Journal article published in 2006 by Shaozhong Wang, Liming Zhang ORCID
This paper is available in a repository.
This paper is available in a repository.

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Abstract

A novel Au-catalyzed migratory cycloisomerization strategy is advanced. Implementation of this strategy led to the development of a unique Au-catalyzed 1,5-enyne cycloisomerizatioin involving carboxy migration and Au-mediated C-C single bond formation. 1-Carboxycyclohexa-1,4-dienes and carboxyarenes can be prepared with good efficiency and with flexible substitution patterns.