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Wiley, Pest Science, 6(55), p. 657-658, 1999

DOI: 10.1002/(sici)1096-9063(199906)55:6<657::aid-ps999>3.0.co;2-7

Wiley, Pest Science, 6(55), p. 657-658

DOI: 10.1002/(sici)1096-9063(199906)55:6<657::aid-ps999>3.3.co;2-z

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Chemical catalysis of the isomerisation of peroxidising herbicidal thiadiazolidines

This paper is available in a repository.
This paper is available in a repository.

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Abstract

Model reactions with various -SH, -OH and -NH nucleophiles in an aprotic solvent were used to characterise the nature of the enzymatic conversion of thiadiazolidines to triazolidines. This conversion results in greater inhibition of protoporphrinogen oxidase (protox). It is inferred that GST-isoforms probably promote formation of one of the intermediates.