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Elsevier, Thermochimica Acta, 1-2(426), p. 199-206

DOI: 10.1016/j.tca.2004.08.001

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Densities, speeds of sound, isentropic compressibilities, refractive indexes, and viscosities of tetrahydrofuran with haloalkane or alkyl ethanoate at T = 303.15 K

Journal article published in 2005 by Sl L. Oswal, Rl L. Gardas ORCID, Rp P. Phalak
This paper is available in a repository.
This paper is available in a repository.

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Abstract

Isentropic compressibilitieS kappa(S), excess isentropic compressibilities K-S(E), excess molar volumes V-E, viscosity deviations Deltaeta, and excess Gibbs energy of activation of viscous flow DeltaG*(E) for nine binary mixtures of C4H8O with CCl4, CHCl3, CHCl2CHCl2, 1-C6H13Cl, 1-C6H13Br, CH3CO2CH3, CH3CO2C2H5, CH3CO2C4H9, and CH3CO2C5H11 at 303.15 K have been derived from experimental densities rho, speeds of sound u, refractive indexes n(D) and viscosities eta. The limiting values of excess partial molar volumes of C4H8O at infinite dilution V-1(E,infinity) in different solvents have been estimated. The results obtained for dynamic viscosity of binary mixtures were used to test the semi-empirical relations of Grunberg-Nissan, Tamura-Kurata, Hind-McLaughlin-Ubbelohde, Katti-Chaudhri, McAllister, Heric, and Auslaender. Finally, the experimental refractive indexes were compared with the predicted results for Lorentz-Lorenz, Dale-Gladstone, Eykman, Arago-Boit, Newton, Oster, Heller, and Wiener equations.