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American Chemical Society, Inorganic Chemistry, 18(49), p. 8444-8448, 2010

DOI: 10.1021/ic1010083

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A Robust Highly Interpenetrated Metal-Organic Framework Constructed from Pentanuclear Clusters for Selective Sorption of Gas Molecules

Journal article published in 2010 by Zhangjing Zhang, Shengchang Xiang ORCID, Yu-Sheng Chen, Shengqian Ma ORCID, Shengqian, Yongwoo Lee, Thomas Phely-Bobin, Banglin Chen
This paper is available in a repository.
This paper is available in a repository.

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Abstract

A three-dimensional microporous metal-organic framework, Zn(5)(BTA)(6)(TDA)(2)·15DMF·8H(2)O (1; HBTA = 1,2,3-benzenetriazole; H(2)TDA = thiophene-2,5-dicarboxylic acid), comprising pentanuclear [Zn(5)] cluster units, was obtained through an one-pot solvothermal reaction of Zn(NO(3))(2), 1,2,3-benzenetriazole, and thiophene-2,5-dicarboxylate. The activated 1 displays type-I N(2) gas sorption behavior with a Langmuir surface area of 607 m(2) g(-1) and exhibits interesting selective gas adsorption for C(2)H(2)/CH(4) and CO(2)/CH(4).