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Wiley-VCH Verlag, ChemInform, 5(44), p. no-no, 2013

DOI: 10.1002/chin.201305075

Wiley, Angewandte Chemie International Edition, 32(51), p. 8092-8096, 2012

DOI: 10.1002/anie.201203224

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Rhodium(III)-Catalyzed Dehydrogenative Heck Reaction of Salicylaldehydes

Journal article published in 2012 by Zhuangzhi Shi ORCID, Nils Schroeder, Nils Schröder, Frank Glorius ORCID
This paper is available in a repository.
This paper is available in a repository.

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Abstract

Your CHOice! An efficient Rh(III) -catalyzed dehydrogenative Heck reaction (DHR) of salicylaldehydes with different classes of olefins extends the oxidative Heck reaction to aldehyde CH bonds. Several structural motifs similar to natural products and bioactive molecules such as aurones, flavones, 2'-hydroxychalcones, and flavanones could be efficiently produced. Initial mechanistic studies give insight into the reaction mechanism.