Published in
Elsevier, Chemical Physics Letters, 1-2(222), p. 135-140
DOI: 10.1016/0009-2614(94)00290-8
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LIF detection of NO3 radical after pulsed excitation of NO2 vapor at 436.45 nm
Journal article published in 1994 by
Sa A. Nizkorodov,
Vi I. Makarov 
,
Iv V. Khmelinskii ,
Sa A. Kotschubei,
Ka A. Amosov
,
Iv V. Khmelinskii ,
Sa A. Kotschubei,
Ka A. Amosov
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Abstract
Single-photon excitation of gaseous NO2 at 436.45 nm at 10−3−101 Torr pressure range has been shown to produce NO3 as an intermediate of NO2 under threshold photolysis. Serious kinetic evidence has been obtained that the formation of NO3 can proceed through the reaction of electronically excited NO2 species with ground state NO2 molecules.