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American Physical Society, Physical Review Letters, 23(93)

DOI: 10.1103/physrevlett.93.237201

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Spin Dynamics in the Carrier-DopedS=12Triangular Lattice ofNaxCoO2·yH2O

Journal article published in 2004 by F. L. Ning ORCID, T. Imai, B. W. Statt, F. C. Chou
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Data provided by SHERPA/RoMEO

Abstract

We probed the local electronic properties of the mixed-valent Co+4-x triangular lattice in NaxCoO2.yH(2)O by 59Co NMR. We observed two distinct types of Co sites for x > or =1/2, but the valence seems averaged out for x approximately 1/3. Local spin fluctuations exhibit qualitatively the same trend down to approximately 100 K regardless of the carrier concentration x, and hence the nature of the electronic ground state. A canonical Fermi-liquid behavior emerges below approximately 100 K only for x approximately 1/3.