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Springer Verlag, Russian Chemical Bulletin, 2(64), p. 284-290

DOI: 10.1007/s11172-015-0858-x

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Novel catalysts for selective hydrogenation of C≡C bond based on Pd nanoparticles immobilized in phenylenecarboxylate frameworks (NH2)-MIL-53(Al)

Journal article published in 2015 by A. Y.-U. Stakheev, V. I. Isaeva, P. V. Markov, O. V. Turova, I. S. Mashkovskii, G. I. Kapustin, B. R. Saifutdinov, L. M. Kustov ORCID
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This paper is available in a repository.

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Abstract

Novel catalysts based on Pd nanoparticles encapsulated into microporous metal-organic framework MIL-53(Al) and NH2-MIL-53(Al) were synthesized. Their catalytic properties were studied in the model reaction of liquid-phase hydrogenation of diphenylacetylene (DPA) (293 K, PH2 = 5 atm). The activity and selectively of the palladium-containing materials Pd—MIL in DPA hydrogenation depend substantially on the nature of the organic linker.