α-MnO2 nanowires were synthesized by a hydrothermal method and then mixed with agglomerated sulfur powders. Homogeneous α-MnO2-coated sulfur particles were obtained by utilizing heat treatment intended to melt and recrystallize the sulfur. α-MnO2 nanowires lead to the suppression in re-agglomeration of sulfur powders during heat treatment and result in successful coating as well as decreased size in parent sulfur powders. The α-MnO2-coated sulfur particles were used as the cathode material for lithium-ion battery applications. Electrochemical evaluation such as the rate capability characteristics and impedance study indicates that the α-MnO2 coated sulfur cathode shows lower resistance and improved rate capability compared to a pristine sulfur cathode.