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Elsevier, Tetrahedron: Asymmetry, 9(19), p. 1084-1093

DOI: 10.1016/j.tetasy.2008.04.009

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Chiral discrimination processes by C9 carbamate derivatives of dihydroquinine: interaction mechanisms of diastereoisomeric 9-O-[(S)- or (R)-1-(1-Naphthyl)ethylcarbamate]dihydroquinine and the two enantiomers of N-(3,5-Dinitrobenzoyl)alanine methyl ester

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Abstract

Computational and NMR investigations of diastereoisomeric aggregates arising from the interaction of 9-O-[(S)- or (R)-1-(1-naphthyl)ethylcarbamate]dihydroquinine and the two enantiomers of N-(3,5-dinitrobenzoyl)alanine methyl ester pointed out the origin of chiral discrimination phenomena occurring in CDCl3 solutions.