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American Chemical Society, Langmuir, 8(25), p. 4247-4250, 2009

DOI: 10.1021/la8038335

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Colloidal Attraction Induced by a Temperature Gradient

Journal article published in 2009 by R. Di Leonardo, F. Ianni, Giancarlo Ruocco ORCID
This paper is available in a repository.
This paper is available in a repository.

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Abstract

Colloidal crystals are of extreme importance for applied research and for fundamental studies in statistical mechanics. Long-range attractive interactions, such as capillary forces, can drive the spontaneous assembly of such mesoscopic ordered structures. However, long-range attractive forces are very rare in the colloidal realm. Here we report a novel strong, long-ranged attraction induced by a thermal gradient in the presence of a wall. By switching the thermal gradient on and off, we can rapidly and reversibly form stable hexagonal 2D crystals. We show that the observed attraction is hydrodynamic in nature and arises from thermally induced slip flow on particle surfaces. We used optical tweezers to measure the force law directly and compare it to an analytical prediction based on Stokes flow driven by Marangoni-like forces.