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American Institute of Physics, Applied Physics Letters, 8(94), p. 083306

DOI: 10.1063/1.3081491

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High efficiency electroluminescence devices using a series of Ir(III)-tetrazolate phosphors: Mechanisms for the drive current evolution of quantum yield

Journal article published in 2009 by Massimo Cocchi, Jan Kalinowski, Stefano Stagni ORCID, Sara Muzzioli
This paper is available in a repository.
This paper is available in a repository.

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Abstract

We demonstrate high-brightness and high-efficiency blue-green to yellow-green electrophosphorescent organic light-emitting diodes employing a series of organic Ir complexes [ Ir- (CN)2(NN)] . Three different complexes have been synthesized showing high photoluminescence solid blend efficiencies up to 44%. A low current density increase of the electroluminescence (EL) external quantum efficiency (φ EL ( ext )) is observed and a maximum of φ EL ( ext )=10.6%±0.8% photon/e and power efficiency η=27±2 lm / W are achieved at a current density of j=0.01 mA / cm 2 . We examine various electronic processes that underlie a nonmonotonous current density dependence of the EL quantum efficiency of electrophosphorescent light-emitting diodes. The shape of φ EL ( ext ) versus j is shown to reflect a trade off between electron-hole encounter and charge carrier transit times, electric field effect on electron-hole pair dissociation time, and current driven triplet molecular exciton lifetime.